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King James Isa 30:33 For Tophet is ordained of old; yea, for the king it is prepared; he hath made it deep and large: the pile thereof is fire and much wood; the breath of the LORD, like a stream of brimstone, doth kindle it.

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Word American Tract Society - Definition
BRIMSTONE A mineral substance, highly inflammable, and burning with a suffocating smell. Sodom and the other cities of the plain were destroyed "by brimstone and fire," Ge 19:24; and this awful catastrophe is often used in Scripture, as an emblem of temporal and eternal judgments of God upon the wicked, Job 18:15; Ps 11:6; Isa 30:33; 34:9; Re 21:8.
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